Al-containing MCM-41 type materials prepared by different synthesis methods: Hydrothermal stability and catalytic properties
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چکیده
منابع مشابه
Synthesis Characterization and Catalytic Evaluation of Mesoporous Fe-MCM-41 and Si-MCM-41 Materials
Environmental concern associated with safe handling disposal of corrosive mineral acids such as HF have encouraged the development of safer and non waste producing alternative for application in catalysis. In this sense ,mesoporous materials attracted much attention of catalysis to transform big molecules into its useful products. In the present study we have synthesized, mesoporous Fe-MCM-41an...
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Temperature-programmed desorption of pyridine, FTIR and multinuclear NMR spectroscopy and catalytic test reaction have been applied to investigate acid sites in mesoporous materials with silicon/aluminum ratios of 266 and 20 and in an amorphous aluminosilicate with nSi/nAl=5.4. The results obtained by these methods indicate the presence of weak Brønsted acid sites in the aluminosilicate samples...
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With the increasingly serious in the energy shortage and environmental problems, biodiesel has been widely studied as a kind of non toxic fuel for renewable and easily biodegradable. Among all kinds of biodiesels, fatty acid ester, obtained from the esterification of oleic acid with alcohol, has received greater attention using as biofuel in recent years [1] [2]. This kind of biodiesel has the ...
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The synthesis and characterization of new molecular sieves of the MCM-41 type are presented in this study. Samples were obtained from the alkoxides of Si, Ti and Al and different long-chain amine and alkylammonium salts surfactants, by the sol-gel method, through moderate agitation at room temperature. The reactions were conducted in two steps, acid hydrolysis (pH=2) and alkaline condensation (...
متن کاملHighly Loaded Fe-MCM-41 Materials: Synthesis and Reducibility Studies
Fe-MCM-41 materials were prepared by different methods. The Fe was both incorporated into the structure and formed crystallites attached to the silica. High Fe content MCM-41 (~16 wt%) with retention of mesoporosity and long-range order was achieved by a range of new synthetic methodologies: (i) by delaying the addition of Fe(aq) to the stirred synthesis gel by 2 h, (ii) by addition of Fe precu...
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ژورنال
عنوان ژورنال: Microporous and Mesoporous Materials
سال: 2006
ISSN: 1387-1811
DOI: 10.1016/j.micromeso.2006.03.020